Typical Wet-spinning solvents and Coagulants.
|
|
|
|
|
|
viscose | rayon | cellulose | aqueous solution of sodium salt and xanthate ester | dilute sulfuric acid + sodium sulfate + zinc sulfate
water |
7-10 |
modal | rayon | aqueous solution of sodium salt and xanthate ester | dilute sulfuric acid + sodium sulfate + zinc sulfate | 10 | |
cupro | cupra | cellulose | aqueous cuprammonium hydroxide | water | |
alginate | calcium salt of alginic acid | aqueous solution of sodium salt of alginic acid | slightly acidic aqueous calcium hydroxide | ||
protein | azlon | arachin, zein, or casein | dilute sodium hydroxide | dilute sulfuric acid + sodium sulfate | |
acrylic | acrylic | copolymer of acrylonitrile
(<85 wt %) with other monomers |
dimethylformamide
dimethylacetamide (DMA)
50% sodium thiocyanate
|
50 % aqueous dimethylformamide
50% aqueous dimethylacetamide
10% sodium thiocyanate
|
17-25 20 20
10-15
|
modacrylic | modacrylic | copolymer of acrylonitrile,
35-85 wt%, with other monomers |
acetone, up to 50% acrylonitrile
dimethylformamide (DMF)
|
aqueous acetone
aqueous dimethylformamide |
15-25 |
vinylal | vinal | poly(vinyl alcohol), posttreated with formaldehyde | water | aqueous sodium sulfate | 10-18 |
aramid | aramid | poly(p-phenylene-
terephthalamide) |
100% sulfuric acid | water or dilute sulfuric acid | 20 |
elastine | spandex | segmented polyurethane | DMF
DMA |
30% aqueous DMF
30% aqueous DMA |
18-30 |
Reference:
Kroschwitz, Jacqueline I. Encyclopedia of Polymer Science and Engineering. Second Edition, Vol. 6. John Wiley & Sons. New York. 1986 pp. 812-815.