UV Curable Coatings:

Ultra Violet Curable coatings use a UV light to initiate crosslinking.  There are no solvents in UV curables, rather oligomers, photoinitiators, reactive diluents (used for crosslinking), and fillers or additives.  The coating that is applied is a viscous liquid, this is due to the reactive diluent and the oligomers units.  Once the coating has been applied to a particular substrate it is flashed with UV light.  The process for cure is either a free radical or cationic mechanism and once fully cured the coating is a high molecular weight, crosslinked, and non-tacky film.  The structures below represents the components of a UV curable system.  All of the components in the UV curable system react and form the polymer coating network.  Therefore 100 percent of the applied coating remains on the substrate once the coating is cured.  No VOCs are emitted after cure and the coating is termed environmetnally friendly.


 
Basic Components of UV Curable Coatings
Component Percent Function
Photoinitiator 1-3 Free radical or cationic initiation
Reactive diluents 15-60 Film formation and viscosity control
Oligomer polymer 25-90 Film formation and basic properties
Additives and fillers 1-50 Surfactants, pigments, stabilizers, etc.
Lamp Source Energy input (cure)

Below are structures of Initiators:

        Free radical


 

        Cationic

      Here are some of the common monomers used in a UV curable system.
 

    N-vinylpyrrolidone
hydroxyethylacrylate
(poly)ethyleneglycol diacrylate
styrene
trimethylolpropanetriacrylate
norbornylacrylate

 
Advantages of UV Curing
100% reactive solids (no solvent)
No decrease in thickness
High chemical resistance
Rapid cure (processing rate ~ 2 m/s)
Low temperature (T<50°C)
Low energy consumption
Reduced process area and equipment

Some of the established applications for UV curable coatings are:  printings inks, metal, textile, platics, wood, and paper coatings, vinyl floors, fiberglass lamenates, photoresists fir printed circuits and microeletronics, photoresists for photochemical machining, moisture vaporbarrier coatings, and photopolymers for printing plates and photolithography.


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