The material developed by Toyota's
researchers
was found to have considerably improved properties, as compared to ordinary
nylon-6. With the addition of just 5% (by weight) clay, the following
property improvements were observed1:
40% higher tensile strength
68% higher tensile modulus
60% higher flexural strength
126% higher flexural modulus
Heat distortion temperature increased from 65o
(nylon-6) to 152oC
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Other researchers have observed the following properties
in other clay nanocomposite systems:
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Increased solvent resistance
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Decreased thermal expansion coefficient
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Reduced permeability
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Flame retardant capability
The reason these figures are so impressive
is that 5% by weight is a very small loading of clay. That is, a
much larger weight fraction of glass fiber, or other reinforcer, would
be needed to achieve this level of performance increase. Perhaps
more impressive is the fact that both strength and toughness are increased.
Usually, increasing tensile strength produces a more brittle material,
and toughened materials lose some of their strength. The addition
of clay, though, can increase both.
How the clay particles achieve these
feats is not well understood, yet. The effect seems to be related
to the clay's enormous surface area, and the
extent of dispersion of the clay in the matrix. Their commercial
potential has made clay nanocomposites the focus of much current research.
Many different polymer matrices have been reinforced with clay in many
laboratories. Matrices researched include polyamides, epoxy
resins, polystyrene,
polyurethanes,
low molecular weight waxes, polypropylene,
poly(N-vinylcarbazole), and more. As yet, only one clay nanocomposite
has been successfully brought into the realm of commercial application,
but clay nanocomposites are sure to play a prominent roll in the future
of high performance materials.
Nanocomposites page 1
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About the author of this page
1. Gilman, Jeffrey W. et al. Nanocomposites: A
Revolutionary New Flame Retardant Approach.